Covalent Organic Frameworks (COF), I understand, is a large molecule where many (block) organic molecules are linked by strong covalent bonds in a periodic or non-periodic manner. It is a nice place where the higher order topological insulating phase is realized as we have pointed out. Then if the COF has boundaries, one can naturally expect edge states/corner states associated with the symmetry protected Berry phases of the bulk. This is correct. One of such a COF, we discussed, is a polymerized triptycene on a decorated star lattice. Our paper ”Flat bands and higher-order topology in polymerized triptycene: Tight-binding analysis on decorated star lattices” by Tomonari Mizoguchi, Mina Maruyama, Susumu Okada, Yasuhiro Hatsugai is for the phenomena and has been published in Physical Review Materials (See also arXiv 1907.06088).




